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Beilstein J. Org. Chem. 2015, 11, 1332–1339, doi:10.3762/bjoc.11.143
Graphical Abstract
Figure 1: Chemical structures of 2-methoxy-1,3,2-dioxaphospholane 2-oxide (1), 2-ethoxy-1,3,2-dioxaphospholan...
Scheme 1: (A) Alkaline hydrolysis of dioxaphospholane: the phosphorane intermediate includes one endocyclic o...
Scheme 2: Reaction of 4 with various Grignard reagents.
Scheme 3: Synthesis of 2-phenyl-1,2-oxaphospholane 2-oxide (5).
Scheme 4: Formation of phosphinates and phosphine oxides bearing three different substituents from oxaphospho...
Scheme 5: Synthesis of acetylene and allene phosphine oxides.